(Butadiene)iron tricarbonyl is an organoiron compound with the formula (C4H6)Fe(CO)3. It is a well-studied metal complex of butadiene.[1] An orange-colored viscous liquid that freezes just below room temperature, the compound adopts a piano stool structure.[2]
Identifiers | |
---|---|
3D model (JSmol) | |
EC Number |
|
PubChem CID | |
| |
| |
Properties | |
C7H6FeO3 | |
Molar mass | 193.967 g·mol−1 |
Appearance | yellow oil |
Melting point | 19 °C (66 °F; 292 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
The complex was first prepared by heating iron pentacarbonyl with the diene.[3]
Related compounds
editIron(0) complexes of conjugated dienes have been extensively studied. In the butadiene series, (η2-C4H6)Fe(CO)4 and (η2:η2-C4H6)(Fe(CO)4)2 have been crystallized.[4] Many related complexes are known for substituted butadienes and related species. The species (η4-isoprene)iron tricarbonyl is chiral.[5]
See also
editReferences
edit- ^ Seyferth, Dietmar (2003). "(Cyclobutadiene)iron Tricarbonyl. A Case of Theory before Experiment". Organometallics. 22: 2–20. doi:10.1021/om020946c.
- ^ Reiss, Guido J. (2010). "Redetermination of (η4-s-cis-1,3-butadiene)tricarbonyliron(0)". Acta Crystallographica Section E. 66 (Pt 11): m1369. doi:10.1107/S1600536810039218. PMC 3009352. PMID 21588810.
- ^ Reihlen, Hans; Gruhl, A.; v. Heßling, G.; O. Pfrengle (1930). "Über Carbonyle und Nitrosyle. IV". Justus Liebigs Annalen der Chemie. 482: 161–182. doi:10.1002/jlac.19304820111.
- ^ Murdoch, H. D.; Weiss, E. (1962). "Butadien-Eisencarbonyl-Verbindungen (Butadieneiron Carbonyl Compounds)". Helvetica Chimica Acta. 45: 1156–61. doi:10.1002/hlca.19620450412.
- ^ Grée, R. (1989). "Acyclic Butadiene-Iron Tricarbonyl Complexes in Organic Synthesis". Synthesis. 1989 (5): 341–355. doi:10.1055/s-1989-27250. S2CID 93030781.
External links
edit- Media related to (Butadiene)iron tricarbonyl at Wikimedia Commons
🔥 Top keywords: Akademia e Shkencave e RPS te ShqiperiseAlexandria Ocasio-CortezBilderberg GroupCristiano RonaldoDong XiaowanMinecraftOperation GladioPrimal cutRiot FestStrictly Come Dancing (series 7)Main PageSpecial:SearchKalki 2898 AD2024 NBA draftWikipedia:Featured picturesUEFA Euro 2024Zaccharie RisacherJulian AssangeBronny JamesICC Men's T20 World CupBill CobbsCleopatra.xxxThe Bear (TV series)Deaths in 20242024 ICC Men's T20 World CupNag AshwinDalton KnechtAlexandre SarrMatas Buzelis2024 Copa AméricaCeline DionThe Boys season 4A Quiet Place: Day OneReed SheppardYouTubeZach EdeyThe Boys (TV series)Shifty ShellshockKalkiRob DillinghamUEFA European ChampionshipHouse of the DragonOpinion polling for the 2024 United Kingdom general electionInside Out 2Stephon CastleCopa AméricaThe Acolyte (TV series)Luis Arce